Getting passport photos taken is arguably one of the least fun aspects of trip preparation (besides actually waiting on line for the passport). The last time I had to get passport pictures taken, I unfortunately chose an extraordinarily busy time at the local drugstore chain, and had to endure getting my photo taken at the front of the store, while everybody in line for the cashier (and for flu shots, mind you) sat and watched.
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Last summer we renewed our passports and took photos using an app called Passport Photos. I printed them at home and they were more than acceptable for our passports and it was FREE! You could also send them up to your local Target or other 1 hour printing place for a fraction of the cost of having them taken. This is an Android app, but I am sure there is also one for iPhone as well.